
%0 Journal Article
%A Gregson, AK 
%A Doddrell, DM 
%A Pegg, DT 
%T Electron spin relaxation in solutions of transition metal ions with S &#8805; 1. Conditions where the Redfield limit is valid
%J Australian Journal of Chemistry
%D 1978/03/01
%V 31
%N 3
%P 469-473
%K 
%R https://doi.org/10.1071/CH9780469
%U https://www.publish.csiro.au/paper/CH9780469 
%X Electron spin relaxation for S = 2 by modulation of the quadratic zero- field splitting under conditions when Te2 > Tl, is treated theoretically. It is shown that the appropriate relaxation matrices when solved numerically yield at high-field strengths two different electron spin relaxation times with different relative weightings. The relative weights are field-dependent, there being only one longitudinal and one transverse relaxation time at low-field strengths. The relaxation matrices for S = 1, 3/2,2,5/2 are summarized in the Appendix. 
