
TY  - JOUR
A1  - Gregson, AK 
A1  - Doddrell, DM 
A1  - Pegg, DT 
T1  - Electron spin relaxation in solutions of transition metal ions with S &#8805; 1. Conditions where the Redfield limit is valid
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1978
VL  - 31
IS  - 3
SP  - 469
EP  - 473
KW  - 
UR  - https://doi.org/10.1071/CH9780469 
N2  - Electron spin relaxation for S = 2 by modulation of the quadratic zero- field splitting under conditions when Te2 > Tl, is treated theoretically. It is shown that the appropriate relaxation matrices when solved numerically yield at high-field strengths two different electron spin relaxation times with different relative weightings. The relative weights are field-dependent, there being only one longitudinal and one transverse relaxation time at low-field strengths. The relaxation matrices for S = 1, 3/2,2,5/2 are summarized in the Appendix. 
ER  -

