
TY  - JOUR
A1  - Pegg, DT 
A1  - Doddrell, DM 
T1  - Electron and nuclear spin relaxation in paramagnetic transition-metal complexes with S = 1. The effects of a non-zero average zero-field splitting on the spin energy levels
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1978
VL  - 31
IS  - 3
SP  - 475
EP  - 481
KW  - 
UR  - https://doi.org/10.1071/CH9780475 
N2  - The effects of a non-zero average zero-field splitting on electron spin relaxation in paramagnetic (S = 1) complexes is treated theoretically. The spin-lattice interaction is postulated to be a simple scalar P(t). S process with correlation time Ti. This process is assumed not to modulate the zero-field splitting which, however, is modulated by the molecular tumbling. The frequency dependence of the nuclear relaxation time (Tl) now depends on the magnitude of the zero-field splitting constant (D), and, for large values of D, the value of T1 is independent of the applied field strength. 
ER  -

