
TY  - JOUR
A1  - Raston, CL 
A1  - Skelton, BW 
A1  - White, AH 
T1  - Structural studies in the phenylmercury/oxinate system
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1978
VL  - 31
IS  - 3
SP  - 537
EP  - 545
KW  - 
UR  - https://doi.org/10.1071/CH9780537 
N2  - The crystal structures of PhHgL [L = quinaldinate, C10H8NO- (1); oxinate, C9H6NO-, two phases, (2) and (3)] have been determined at 295 K and refined by least squares to residuals of 0.068 (2148 'observed' reflections) for (1), 0.107 (1165) for (2) and 0.046 (1146) for (3). Crystals of (1) are mono-clinic, C2/c, a 22.961(8), b 9.142(2), c 16.412(6) &#506;, &#946; 127.75(2)&#176;, Z 8; those of (2) are orthorhombic, Pnam, a 23.12(3), b 16.59(2), c 6.62(1) &#506;, Z 8; those of (3) are orthorhombic, P212121, a 5.584(2), b 9.902(3), c 22.073(9) &#506;, Z 4.     In (1) the molecules are grouped as loose dimeric associations about a twofold axis with Hg...O bridges. In (2) the molecules lie stacked in a loose infinite array along c, while in (3) the disposition is an infinite helical array; in both (2) and (3), the Hg...O contacts are very long. 
ER  -

