
%0 Journal Article
%A Mitra, S 
%A Raston, CL 
%A White, AH 
%T Crystal structure of Tris(pyrrolidine-1-carbodithioato)iron(III)
%J Australian Journal of Chemistry
%D 1978/03/01
%V 31
%N 3
%P 547-553
%K 
%R https://doi.org/10.1071/CH9780547
%U https://www.publish.csiro.au/paper/CH9780547 
%X The crystal structure of the title compound, [Fe{CS2N(CH2)4}3] (a new phase prepared from chloro-form/toluene solutions), has been determined by single-crystal X-ray diffraction at 295 K and refined to a residual of 0.059 for 5651 'observed' reflections. Crystals are monoclinic, P21/a, a 18.033(6), b 9.398(2), c 13.176(6) &#506;, &#946; 100.80(3)&#176;, Z 4. The compound is a purely high-spin derivative, the iron atom being in the usual pseudo-D3 environment with <Fe-S> very long (2.456 &#506;). 
