
%0 Journal Article
%A Lemieux, RU 
%A Stick, RV 
%T A synthesis of 3-O-(2-Acetamido-2-deoxy-&#945;-D-galactopyranosyl)-D-galactopyranose and 3-O-&#945;-D-Galactopyranosyl-D-galactopyranose
%J Australian Journal of Chemistry
%D 1978/04/01
%V 31
%N 4
%P 901-905
%K 
%R https://doi.org/10.1071/CH9780901
%U https://www.publish.csiro.au/paper/CH9780901 
%X The condensation of 1,2:5,6-di-O-isopropylidene-&#945;-D-galactose with dimeric tri-O-acetyl-2-deoxy-2-nitroso-&#945;-D-galactopyranosyl chloride gives 3-O-(tri-O-acetyl-2-hydroxyimino-&#945;-D-lyxo-hexopyranosyl)-1,2:5,6- di-O-isopropylidene-&#945;-D-galactose. This hydroxyimino glycoside may then be converted, by an established reductive sequence, into the title 2- acetamido-2-deoxydisaccharide and its talo epimer. Alternatively, hydrolysis of the hydroxyimino glycoside yields a ketone which, again by an established reductive sequence, may be converted into the title disaccharide and its talo epimer. 
