
TY  - JOUR
A1  - Lemieux, RU 
A1  - Stick, RV 
T1  - A synthesis of 3-O-(2-Acetamido-2-deoxy-&#945;-D-galactopyranosyl)-D-galactopyranose and 3-O-&#945;-D-Galactopyranosyl-D-galactopyranose
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1978
VL  - 31
IS  - 4
SP  - 901
EP  - 905
KW  - 
UR  - https://doi.org/10.1071/CH9780901 
N2  - The condensation of 1,2:5,6-di-O-isopropylidene-&#945;-D-galactose with dimeric tri-O-acetyl-2-deoxy-2-nitroso-&#945;-D-galactopyranosyl chloride gives 3-O-(tri-O-acetyl-2-hydroxyimino-&#945;-D-lyxo-hexopyranosyl)-1,2:5,6- di-O-isopropylidene-&#945;-D-galactose. This hydroxyimino glycoside may then be converted, by an established reductive sequence, into the title 2- acetamido-2-deoxydisaccharide and its talo epimer. Alternatively, hydrolysis of the hydroxyimino glycoside yields a ketone which, again by an established reductive sequence, may be converted into the title disaccharide and its talo epimer. 
ER  -

