
TY  - JOUR
A1  - Malhotra, KC 
A1  - Mehrotra, G 
A1  - Mahajan, VP 
A1  - Chaudhry, SC 
T1  - Solvolytic reactions of Lewis acids in dichloroacetic acid and the nature of the solvolysed products
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1978
VL  - 31
IS  - 5
SP  - 967
EP  - 971
KW  - 
UR  - https://doi.org/10.1071/CH9780967 
N2  - Tetrachlorides of tin, titanium, zirconium, thorium and silicon form compounds of composition SnCl2(CHCl2COO)2, Ti(CHCl2COO)4, Zr(CHCl2COO)4, Th(CHCl2COO)4 and Si2O(CHCl2COO)6 when refluxed with excess of dichloroacetic acid. From i.r., molecular weight and conductance studies, their structures have been elucidated. Their Lewis acid character is established by isolating and characterizing their adducts with organic tertiary bases. Antimony pentachloride, aluminium trichloride and iron(III) trichloride form compounds of composition SbCl2(CHCl2COO)3, Al(CHCl2COO)3 and FeCl(CHCl2COO)2 when refluxed with excess of the solvent and these have been characterized by i.r. studies. 
ER  -

