
%0 Journal Article
%A Brown, DJ 
%A .Waring, P 
%T Pyrimidine reactions. XXVII. Syntheses, reactivities and mass spectra of some 2-isopropylpyrimidine derivatives
%J Australian Journal of Chemistry
%D 1978/06/01
%V 31
%N 6
%P 1391-1395
%K 
%R https://doi.org/10.1071/CH9781391
%U https://www.publish.csiro.au/paper/CH9781391 
%X Syntheses of 2-(1'-bromo-1'-methylethyl)-4-chloropyrimidine (1c) and its 4-fluoro analogue (1f) are described. Rates for solvolysis of these and similar bromo compounds in 50% aqueous methanol at pH 7.0 are recorded at several temperatures. These data and some unusual facets of the mass spectra shown by 2-isopropylpyrimidines, and their &#945;-bromo or &#945;-methoxy derivatives, are discussed. 
