
TY  - JOUR
A1  - Coxon, JM 
A1  - Projer, PM 
A1  - Steel, PJ 
A1  - Rae, ID 
A1  - Jones, AJ 
T1  - A study of the reactions of 2-Aryl-3,3-dimethylbicyclo[2,2,1]heptan-2-ols with acid
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1978
VL  - 31
IS  - 8
SP  - 1747
EP  - 1755
KW  - 
UR  - https://doi.org/10.1071/CH9781747 
N2  - The 13C and 1H N.M.R. spectra of a series of 2-aryl-3,3- dimethylbicyclo[2,2,1]hept-2-yl cations generated in strong acid at low temperatures are reported. The chemical shifts of carbons proximate to the cation centres are discussed with reference to related cations. At higher temperatures, 2-aryl-3,3-dimethylbicyclo[2,2,1]hept-2-yl cations in fluorosulfonic acid give substituted 7,8-dimethyltetracyclo- [7,4,0,02,7,04,8]trideca-1(9),10,12-trienesulfonyl fluorides. Substituted 7,8-dimethyltetracyclo[7,4,0,-02,7,04,8]trideca-1(9),10,12-trienes and 7,8-dimethyltetracyclo[7,4,0,02,7,04,8]trideca-1(9),10,12-triene were prepared from 2-aryl-3,3-dimethylbicyclo[2,2,1]heptan-2-ols by reaction with perchloric acid under carefully controlled conditions. 
ER  -

