
%0 Journal Article
%A Kepert, DL 
%A Raston, CL 
%A Roberts, NK 
%A White, AH 
%T Crystal structure of Tris(N,N-diethyldithiocarbamato)thallium(III)
%J Australian Journal of Chemistry
%D 1978/09/01
%V 31
%N 9
%P 1927-1932
%K 
%R https://doi.org/10.1071/CH9781927
%U https://www.publish.csiro.au/paper/CH9781927 
%X The crystal structure of the title compound, [Tl(S2CNEt2)3], has been determined by single-crystal X-ray diffraction methods at 295 K and refined by full-matrix least squares to a residual of 0.050 for 2517 'observed' reflections. Crystals are monoclinic, with space group A2/a, a 14.789(7), b 10.428(4), c 18.207(9) &#506;, &#946; 118.11(4)&#176;, Z 4, and are isostructural with those of the previously determined gallium and indium analogues, the molecule having 2 symmetry with <Tl-S> 2.666 &#506;. As in the dimethyl/thallium analogue, the departure of the TlS6 core symmetry from 3 is large and is examined in terms of electron-pair repulsion theory. 
