
TY  - JOUR
A1  - Kepert, DL 
A1  - Raston, CL 
A1  - Roberts, NK 
A1  - White, AH 
T1  - Crystal structure of Tris(N,N-diethyldithiocarbamato)thallium(III)
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1978
VL  - 31
IS  - 9
SP  - 1927
EP  - 1932
KW  - 
UR  - https://doi.org/10.1071/CH9781927 
N2  - The crystal structure of the title compound, [Tl(S2CNEt2)3], has been determined by single-crystal X-ray diffraction methods at 295 K and refined by full-matrix least squares to a residual of 0.050 for 2517 'observed' reflections. Crystals are monoclinic, with space group A2/a, a 14.789(7), b 10.428(4), c 18.207(9) &#506;, &#946; 118.11(4)&#176;, Z 4, and are isostructural with those of the previously determined gallium and indium analogues, the molecule having 2 symmetry with <Tl-S> 2.666 &#506;. As in the dimethyl/thallium analogue, the departure of the TlS6 core symmetry from 3 is large and is examined in terms of electron-pair repulsion theory. 
ER  -

