
%0 Journal Article
%A Prager, RH 
%A Tippett, JM 
%A Ward, AD 
%T Relative migratory aptitudes in the Schmidt reaction of arylpropanones and 2-arylcyclohexanones
%J Australian Journal of Chemistry
%D 1978/09/01
%V 31
%N 9
%P 1989-2001
%K 
%R https://doi.org/10.1071/CH9781989
%U https://www.publish.csiro.au/paper/CH9781989 
%X The relative migratory aptitude of benzyl and alkyl groups in the reaction of arylpropanones and 2-arylcyclohexanones with hydrazoic acid depends on the solvent, temperature and nature of the substituents in the aryl ring. It is suggested that at low temperatures electron- donating groups in the aromatic ring favour a charge-transfer interaction which affects the relative migratory aptitudes. 
