
TY  - JOUR
A1  - Prager, RH 
A1  - Tippett, JM 
A1  - Ward, AD 
T1  - Relative migratory aptitudes in the Schmidt reaction of arylpropanones and 2-arylcyclohexanones
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1978
VL  - 31
IS  - 9
SP  - 1989
EP  - 2001
KW  - 
UR  - https://doi.org/10.1071/CH9781989 
N2  - The relative migratory aptitude of benzyl and alkyl groups in the reaction of arylpropanones and 2-arylcyclohexanones with hydrazoic acid depends on the solvent, temperature and nature of the substituents in the aryl ring. It is suggested that at low temperatures electron- donating groups in the aromatic ring favour a charge-transfer interaction which affects the relative migratory aptitudes. 
ER  -

