
%0 Journal Article
%A Raston, CL 
%A White, AH 
%A Winter, G 
%T Crystal structure of Tetraethylammonium Tetrakis(O-ethylxanthato)bismuthate(III)
%J Australian Journal of Chemistry
%D 1978/10/01
%V 31
%N 10
%P 2207-2212
%K 
%R https://doi.org/10.1071/CH9782207
%U https://www.publish.csiro.au/paper/CH9782207 
%X The crystal structure of the title compound (NEt4) [Bi(S2COEt)4] has been determined by single-crystal X-ray diffraction at 295(1) K and refined by least squares to a residual of 0.051 for 1560 'observed' reflections. Crystals are monoclinic, P21, a 10.947(2), b 16.334(4), c 10.589(2)&#506;, &#946; 116.04(2)&#176;, Z 2. The bismuth coordination stereochemistry is dodecahedral, Bi-S ranging from 2.803(11) to 2.972(10) &#506;; the three longest distances occupy a triangular face in the coordination polyhedron and may indicate the presence of a stereochemically active lone pair. 
