
%0 Journal Article
%A Black, DSC 
%A Doyle, JE 
%T The limited scope of azabicyclohexane synthesis from &#948;,&#949;-unsaturated amines
%J Australian Journal of Chemistry
%D 1978/10/01
%V 31
%N 10
%P 2247-2257
%K 
%R https://doi.org/10.1071/CH9782247
%U https://www.publish.csiro.au/paper/CH9782247 
%X The reported synthesis of 1-azabicyclo[3,1,0]hexanes from &#946;,&#946;-diphenyl &#948;,&#949;-unsaturated alkylamines has been verified and extended. However, similar treatment of alkyl-substituted &#948;,&#949;-unsaturated alkylamines with bromine and sodium hydride fails to afford azabicyclohexanes and unsaturated acyclic products are formed. It is concluded that satisfactory synthesis of azabicyclohexanes from &#948;,&#949;-unsaturated amines is contingent on the presence of suitable bulky substituents. 
