
TY  - JOUR
A1  - Black, DSC 
A1  - Doyle, JE 
T1  - The limited scope of azabicyclohexane synthesis from &#948;,&#949;-unsaturated amines
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1978
VL  - 31
IS  - 10
SP  - 2247
EP  - 2257
KW  - 
UR  - https://doi.org/10.1071/CH9782247 
N2  - The reported synthesis of 1-azabicyclo[3,1,0]hexanes from &#946;,&#946;-diphenyl &#948;,&#949;-unsaturated alkylamines has been verified and extended. However, similar treatment of alkyl-substituted &#948;,&#949;-unsaturated alkylamines with bromine and sodium hydride fails to afford azabicyclohexanes and unsaturated acyclic products are formed. It is concluded that satisfactory synthesis of azabicyclohexanes from &#948;,&#949;-unsaturated amines is contingent on the presence of suitable bulky substituents. 
ER  -

