
%0 Journal Article
%A Figgis, BN 
%A Raston, CL 
%A Sharma, RP 
%A White, AH 
%T Crystal structure of Tris(pyridine-2-carboxylato)manganese(III) monohydrate
%J Australian Journal of Chemistry
%D 1978/11/01
%V 31
%N 11
%P 2545-2548
%K 
%R https://doi.org/10.1071/CH9782545
%U https://www.publish.csiro.au/paper/CH9782545 
%X The crystal structure of the title compound, [Mn(C5H4NCO2)3],H2O, has been determined by single-crystal X-ray diffraction at 295 K and refined by least squares to a residual of 0.053 for 2234 'observed' reflections. Crystals are monoclinic, C2/c, a 30.50(2), b 8.387(8), c 13.903(7) &#506;, &#946; 94.15(3)&#176;, Z 8. The geometry of the manganese environment displays a pseudo-tetragonal distortion, the axial atoms being nitrogen (Mn-N 2.254(6), 2.217(6) &#506;). The equatorial atoms are at distances Mn-N 2.059(5) &#506;, Mn-O 1.891(5), 1.908(5), 1.942(5) &#506;, the latter being trans to the nitrogen. The occupancy of the water molecule site is 0.54(1). 
