
TY  - JOUR
A1  - Dyall, LK 
A1  - Pullin, CJ 
T1  - The Relative Reactivities of the Seven Nuclear Positions of Isoquinoline to Free-Radical Phenylation
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1979
VL  - 32
IS  - 2
SP  - 345
EP  - 352
KW  - 
UR  - https://doi.org/10.1071/CH9790345 
N2  - Free-radical phenylation of isoquinoline has been effected both by photolysis of phenylthallium(III) di(trifluoroacetate) and by the action of pentyl nitrite on aniline. Analysis of the isomeric phenyl isoquinoline mixture by g.l.c. and h.p.l.c. established the reactivity order in the isoquinoline nucleus to be 1 > 5 > 8 > 4 > 3,6,7. This experimental order is compared with the eight published theoretical predictions, none of which is correct. 
ER  -

