
TY  - JOUR
A1  - Patroni, JJ 
A1  - Stick, RV 
T1  - Stereoselective Reduction of 3-O-Hexofuranosyl S-Methyl Dithiocarbonates with Tributyltin Deuteride
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1979
VL  - 32
IS  - 2
SP  - 411
EP  - 416
KW  - 
UR  - https://doi.org/10.1071/CH9790411 
N2  - The reduction of several 3-O-hexofuranosyl (gluco, allo, galacto, gulo) S-methyl dithiocarbonates with tributyltin deuteride leads to highly stereoselective syntheses of 3-deoxy-[3-2H]hexofuranoses.Correspondingly, the reduction of the 3-O-[3-2H]hexofuranosyl (allo, gulo) S-methyl dithiocarbonates with tributyltin hydride leads to the epimeric (C3) 3-deoxy-[3-2H]hexofuranoses, and the reduction with tributyltin deuteride leads to the 3-deoxy-[3,3-2H2]hexofuranose. 
ER  -

