
TY  - JOUR
A1  - Khurma, JR 
A1  - Fenby, DV 
T1  - Thermodynamics of Deuterium Exchange Reactions in Water-Thiol and Alcohol-Thiol Systems
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1979
VL  - 32
IS  - 4
SP  - 755
EP  - 759
KW  - 
UR  - https://doi.org/10.1071/CH9790755 
N2  - Thermodynamic properties at 298 K are obtained for the deuterium exchange reactions     RSH + SHD &#8594; O + RSD + H2O   RSH + DO2 &#8594; O + RSD + HDO   RSH + R?OD &#8594; O + RSD + R?OH    Equilibrium constants and enthalpies of the gas phase reactions with R = R' = CH3 are calculated from statistical mechanical equations using recently published harmonic frequencies. Experimental properties, including the molar excess enthalpies of C2H5SH + CH3OH, C2H5SH + CH3OD, C2H5SH + C2H5OH and C2H5SH + C2H5OD reported in this paper, are used to obtain the equilibrium constants and enthalpies of the liquid and gas phase reactions with R = C2H5, R' = CH3 and C2H5. 
ER  -

