
TY  - JOUR
A1  - Bird, GJ 
A1  - Collins, DJ 
A1  - Eastwood, FW 
A1  - Exner, RH 
A1  - Romanelli, ML 
A1  - Small, DD 
T1  - The Synthesis of (25R)-22&#945;N-[15&#958;,17&#945;-<sup>2</sup>H<sub>2</sub>]-Spirosol-5-en-3&#946;-ol ([15&#958;,17&#945;-<sup>2</sup>H<sub>2</sub>] Solasodine) and Assignment of the <sup>13</sup>C N.M.R. Spectra of Solasodine and its Derivatives
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1979
VL  - 32
IS  - 4
SP  - 783
EP  - 796
KW  - 
UR  - https://doi.org/10.1071/CH9790783 
N2  - (25R)-22&#945;N-[15&#950;,17&#945;-2H2]Spirosol-5-en-3&#946;-ol ([15&#950;,17&#945;-2H2]solasodine) has been synthesized from solasodine and used to make unambiguous assignments of the resonance signals for C13, C14, C15, C17 and C20 in the 13C N.M.R. spectrum of solasodine. The complete assignments of the 13C N.M.R. spectra of solasodine and some of its derivatives are based on this, on paramagnetic broadening of signals due to C22, C23, C25 and C26, and on chemical shift considerations. 
ER  -

