
%0 Journal Article
%A Arthur, NL 
%A Christie, JR 
%A Mitchell, GD 
%T Reactions of Trifluoromethyl Radicals. IV. Hydrogen Abstraction from Dichlorosilane and Trichlorosilane
%J Australian Journal of Chemistry
%D 1979/05/01
%V 32
%N 5
%P 1017-1023
%K 
%R https://doi.org/10.1071/CH9791017
%U https://www.publish.csiro.au/paper/CH9791017 
%X The hydrogen abstraction reactions of SiH2Cl2 and SiHCl2 with CF3 radicals  CF3+SiH2Cl2 &#8594; CF3H + SiHCl2 CF3+SiH2Cl3 &#8594; CF3H + SiHCl3 have been studied in the temperature ranges 65-227ºand 64-294º, respectively. The rate constants, based on the value of 1013.36 cm3 mol-1 s-1 for the recombination of CF3 radicals, are given by (k in cm3 mol-1 s-1, E in J mol-1): logk1 = (12.08 ± 0.04)-(25600 ± 280)/19.145T logk2 = (11.92 ± 0.02)-(27020 ± 160)/19.145T 
