
TY  - JOUR
A1  - Broxton, TJ 
T1  - Reactions of Aryl Diazonium Salts and Arylazo Alkyl Ethers. IV. Substituent Effects on the Rates of Some Reactions of <I>syn</I>-Arylazo Ethyl Ethers in Ethanol
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1979
VL  - 32
IS  - 5
SP  - 1031
EP  - 1037
KW  - 
UR  - https://doi.org/10.1071/CH9791031 
N2  - Substituent effects on the rates of ionization (kIS), decomposition (kD) and syn-anti interconversion (kp) for a number of syn-arylazo ethyl ethers have been measured. The rates of ionization and syn-anti interconversion correlate well with sigma while the rates of decomposition correlate with &#963;+. Substituent effects on the ionization of the syn-ethers are compared to those for ionization of the anti-ethers. Substituent effects on the rate of syn-anti interconversion support the proposed ionization-recombination mechanism. 
ER  -

