
TY  - JOUR
A1  - Sadanani, ND 
A1  - Walia, A 
A1  - Kapoor, PN 
A1  - Kapoor, RN 
T1  - Transition Metal Complexes of [2-{Di(<I>m</I>-tolyl)phosphino}ethyl]diphenylphosphine
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1979
VL  - 32
IS  - 5
SP  - 1143
EP  - 1148
KW  - 
UR  - https://doi.org/10.1071/CH9791143 
N2  - The 1 : 1 complexes of chelating diphosphine, [2-{di(m-tolyl)phosphino}ethyl]diphenylphosphine (pmtpf), with nickel(II), palladium(II) and platinum(II) halides and thiocyanates and 2 : 1 complexes with nickel(II) perchlorates have been prepared. Ligand (pmtpf) forms low-spin square-planar and diamagnetic [M(pmtpf)X2](where X = Cl, Br, I or NCS; M = Ni, Pd or Pt) and [Ni(pmtpf)2]- (ClO4)2 complexes. Complexes of metal carbonyls having the general formula [(pmtpf)M(CO)4] (where M = Cr, Mo or W) have also been synthesized. These complexes have been characterized on the basis of element analysis, electronic, infrared and 1H N.M.R. spectral measurements, magnetic susceptibilities and electrical conductance data. In all cases studied this ligand acts as a chelating ditertiary phosphine. 
ER  -

