
%0 Journal Article
%A Bowmaker, GA 
%A Tan, L 
%T The Preparation and Low-Frequency Vibrational Spectra of Some Copper(I) and Silver(I) Alkane- and Arene-monothiolate Complexes
%J Australian Journal of Chemistry
%D 1979/07/01
%V 32
%N 7
%P 1443-1452
%K 
%R https://doi.org/10.1071/CH9791443
%U https://www.publish.csiro.au/paper/CH9791443 
%X A number of different methods for preparing anionic Group 1B metal thiolate complexes have been investigated. The compounds [Me4N] [CU2(SMe)3] and [Et4N] [Ag5(SBut)6] are reported for the first time, and new methods for preparing the previously known compounds [Et4N] [Cu5(SBut)6], [Me4N]2 [CU5(SPh)7] and [Et4N]2 [Cu5(SPh)7] are described. The far-infrared spectra of the above compounds, and of CuSMe, CuSBut, AgSBut, [Me4N]2 [CU4(SPh)6] and [Me4N]2 [Ag5(SPh)7] have been obtained, and metal-sulfur stretching bands are assigned in the 150-350 cm-1 region. The low-frequency Raman spectra have also been obtained for some of these compounds. Possible structures for the new compounds are considered in the light of the low-frequency vibrational spectra. 
