
%0 Journal Article
%A Koner, ZS 
%A Phutela, RC 
%A Fenby, DV 
%T Determination of the equilibrium constants of water-methanol deuterium exchange reactions from vapour pressure measurements
%J Australian Journal of Chemistry
%D 1980/01/01
%V 33
%N 1
%P 9-13
%K 
%R https://doi.org/10.1071/CH9800009
%U https://www.publish.csiro.au/paper/CH9800009 
%X The equilibrium constant of the reaction2CH3OH(l) + D2O(l) &#8594; 2CH3OD(l) + H2O(l) is obtained from vapour pressure measurements. The value, 1.09k0.02 at 298 K, is in satisfactory agreement with calculated values and with calorimetric estimates. Vapour pressures at 298.14 K are reported for the systems H2O + CH3OH, H2O+CH3OD, D2O + CH3OH and D2O+ CH3OD. Molar excess Gibbs functions are obtained from these vapour pressures. 
