
TY  - JOUR
A1  - Adcock, W 
A1  - Abeywickrema, AN 
T1  - Conformational preference of the fluoromethyl group in some benzyl fluorides: a <sup>13</sup>C N.M.R. study
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1980
VL  - 33
IS  - 1
SP  - 181
EP  - 187
KW  - 
UR  - https://doi.org/10.1071/CH9800181 
N2  - A number of model benzyl fluoride systems have been synthesized, and their proton-decoupled natural-abundance 13C n.m.r. spectra recorded and assigned. An analysis of the long-range five-bond coupling constants (5JCF) indicates that these parameters are predominantly a manifestation of hyperconjugation involving the CF &#963; bond. The utilization of these parameters as conformational probes is demonstrated. 
ER  -

