
TY  - JOUR
A1  - Bruce, MI 
A1  - Kelly, DA 
A1  - Mclaughlin, GM 
A1  - Robertson, GB 
A1  - Tomkins, IB 
A1  - Wallis, RC 
T1  - Reactions between ruthenium chlorides and trimethyl phosphite : crystal and molecular structures of RuCI3(NH3)[P(OMe)3]2
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1980
VL  - 33
IS  - 1
SP  - 195
EP  - 201
KW  - 
UR  - https://doi.org/10.1071/CH9800195 
N2  - The reaction between RuCl3,nH2O and P(OMe)3 affords RuCl2[P(OMe)3]4; one batch of RuCl3,-nH2O also gave amminetrichlorobis(trimethyl phosphite)ruthenium(III), RuCl3(NH3)[P(OMe)3]2, as a minor product. The structure of this complex has been determined from a single-crystal X-ray diffraction study (4598 data, R 0.065, Rw 0.090): the ruthenium is approximately octahedrally coordinated by the three mer chloro, two trans P(OMe)3 and one NH3 ligands. Crystals are monoclinic,P21/n, a 8.725(3), b 18.286(7), c 10.936(4)&#506;, &#946; 94.57(3)&#176;, Z 4. 
ER  -

