
TY  - JOUR
A1  - Rosevear, J 
A1  - Wilshire, JFK 
T1  - The chlorination of some N,N-Dimethylanilines with 1,3,5-Trichloro-1,3,5-triazine-2,4,6(1H,3H,5H)-trione (Trichloroisocyanuric acid)
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1980
VL  - 33
IS  - 4
SP  - 843
EP  - 852
KW  - 
UR  - https://doi.org/10.1071/CH9800843 
N2  - The reaction of some representative N,N-dimethylanilines and of Fischer's base (1,3,3-trimethyl-2-methyleneindoline) with trichloroisocyanuric acid in concentrated sulfuric acid has been investigated. In many cases mixtures of chlorinated products were obtained; these mixtures were examined both by gas-liquid chromatography and by proton magnetic resonance spectroscopy. The reaction of N,N-dimethylaniline with dichloroisocyanuric acid was also studied.      A feature of these chlorinations is the marked tendency for substitution to occur ortho to the dimethylamino group. This behaviour therefore differs from that reported for the corresponding brominations involving dibromoisocyanuric acid, where meta-substitution was observed. 
ER  -

