
%0 Journal Article
%A Raston, CL 
%A White, AH 
%A Yandell, JK 
%T Crystal structure of <I>trans</I>-Amminebis(ethane-1,2-diamine)sulfitocobalt(III) perchlorate
%J Australian Journal of Chemistry
%D 1980/05/01
%V 33
%N 5
%P 1123-1128
%K 
%R https://doi.org/10.1071/CH9801123
%U https://www.publish.csiro.au/paper/CH9801123 
%X The crystal structure of the title compound, trans- [Co(C2N2H8)2(NH3)(SO3)] ClO4, has been determined by single-crystal X-ray diffraction methods at 295(1)K and refined by least squares to a residual of 0.061 for 2989 'observed' reflections. Crystals are monoclinic, P21/n, a 6.863(3), b 14.713(6), c 13.279(8) &#506;, &#946; 104.45(4)&#176;, Z 4. Whereas the Co-S bond has the common value of 2.227(2) &#506;, Co-N is remarkably long, being 2.070(3) &#506;, this being ascribed to a structural trans effect. 
