
TY  - JOUR
A1  - Raston, CL 
A1  - White, AH 
A1  - Yandell, JK 
T1  - Crystal structure of <I>trans</I>-Amminebis(ethane-1,2-diamine)sulfitocobalt(III) perchlorate
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1980
VL  - 33
IS  - 5
SP  - 1123
EP  - 1128
KW  - 
UR  - https://doi.org/10.1071/CH9801123 
N2  - The crystal structure of the title compound, trans- [Co(C2N2H8)2(NH3)(SO3)] ClO4, has been determined by single-crystal X-ray diffraction methods at 295(1)K and refined by least squares to a residual of 0.061 for 2989 'observed' reflections. Crystals are monoclinic, P21/n, a 6.863(3), b 14.713(6), c 13.279(8) &#506;, &#946; 104.45(4)&#176;, Z 4. Whereas the Co-S bond has the common value of 2.227(2) &#506;, Co-N is remarkably long, being 2.070(3) &#506;, this being ascribed to a structural trans effect. 
ER  -

