
%0 Journal Article
%A Trenerry, VC 
%A Blair, IA 
%A Bowie, JH 
%T Ion-cyclotron resonance studies of alkylsilyl ions. VI. The reactions of 2,2-dimethylpropan-1-ol and 1-methoxy-2,2-dimethylpropane with the trimethylsilyl cation
%J Australian Journal of Chemistry
%D 1980/05/01
%V 33
%N 5
%P 1143-1146
%K 
%R https://doi.org/10.1071/CH9801143
%U https://www.publish.csiro.au/paper/CH9801143 
%X The trimethylsilyl cation forms 1 : 1 adducts with both 2,2- dimethylpropan-1-ol and 1-methoxy-2,2-dimethylpropane, with both adducts eliminating C5H10 by (at least) two mechanisms. One mechanism involves a 1,2-hydride transfer from the carbon &#945; to oxygen to the oxygen acceptor site; the other a 1,4-transfer from a &#947;-carbon substituent. 
