
TY  - JOUR
A1  - Trenerry, VC 
A1  - Blair, IA 
A1  - Bowie, JH 
T1  - Ion-cyclotron resonance studies of alkylsilyl ions. VI. The reactions of 2,2-dimethylpropan-1-ol and 1-methoxy-2,2-dimethylpropane with the trimethylsilyl cation
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1980
VL  - 33
IS  - 5
SP  - 1143
EP  - 1146
KW  - 
UR  - https://doi.org/10.1071/CH9801143 
N2  - The trimethylsilyl cation forms 1 : 1 adducts with both 2,2- dimethylpropan-1-ol and 1-methoxy-2,2-dimethylpropane, with both adducts eliminating C5H10 by (at least) two mechanisms. One mechanism involves a 1,2-hydride transfer from the carbon &#945; to oxygen to the oxygen acceptor site; the other a 1,4-transfer from a &#947;-carbon substituent. 
ER  -

