
TY  - JOUR
A1  - Poh, B 
T1  - A quantitative analysis of solvent effects on reaction constant
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1980
VL  - 33
IS  - 6
SP  - 1175
EP  - 1186
KW  - 
UR  - https://doi.org/10.1071/CH9801175 
N2  - Solvent effects on reaction constant &#961; for the dissociation equilibria of several series of organic acids are analysed in terms of three factors, namely, (i) variation in the effective dielectric constant, (ii) variation in the hydrogen-bonding ability of solvents, and (iii) variation in the conformation of the acids. A fourth factor, variation in the charge developed in the transition state of the reaction, is included in the analysis of &#961; for reactions between diazodiphenylmethane and several series of carboxylic acids. It is shown that the &#961; values for the dissociation equilibria of series of acids in other solvents can be calculated from their &#961; values in water. 
ER  -

