
TY  - JOUR
A1  - Morgan, KR 
A1  - Curtis, NF 
T1  - Some metal-ion complexes with ligands formed by reactions of amines with aliphatic carbonyl compounds. X. Compounds of some tridentate ligands formed by reaction of copper(II) 2-Aminoethanol and 3-Aminopropan-1-ol complexes with 4-Amino-(and 4-Hydroxy)-4-methylpentan-2-one
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1980
VL  - 33
IS  - 8
SP  - 1695
EP  - 1703
KW  - 
UR  - https://doi.org/10.1071/CH9801695 
N2  - Compounds of copper(II) perchlorate with 2-aminoethanol (etol) and 3- aminopropan-1-ol (prol) react with 4-amino-4-methylpropan-2-one (amp), and with 4-hydroxy-4-methylpropan-2-one (hmp), to form compounds of stoichiometry [Cu(L)] ClO4, where (L) is a tridentate amine imine olato ligand from amp, or a hydroxy imine olato ligand from hmp. The etol condensation products have 'normal' magnetic susceptibilities, while the prol condensation products show antiferromagnetic spin-coupling. The prol/amp product is diamagnetic at 300 K (-J > 700 cm-1) and the prol/hmp product has a J of -186 cm-1, based on magnetic susceptibility measurements over 100-300 K. Preparations of some related nitrate, thiocyanate and tetrachlorozincate compounds are reported. Possible structures for the compounds are discussed. 
ER  -

