
TY  - JOUR
A1  - Westcott, TJ 
A1  - White, AH 
A1  - Willis, AC 
T1  - Crystal structure of <I>trans</I>-tetraamminebis(isothiocyanato)cobalt(III) acetate-acetic, acid (III)
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1980
VL  - 33
IS  - 8
SP  - 1853
EP  - 1856
KW  - 
UR  - https://doi.org/10.1071/CH9801853 
N2  - The crystal structure of the title compound, trans-[Co(NH3)4(NCS)2] O2CCH3,HO2CCH3, has been determined at 295(1) K by single-crystal X-ray diffraction and refined by least squares to a residual of 0.11 for 300 'observed' reflections. Crystals are orthorhombic, Pbam, a 14.851(9), b 7.068(4), c 7.031(4) &#506;, Z 2. The cation is centred at the origin of the cell with cobalt site symmetry 2/m, so that only one ammonia and one- half of the N-bonded thiocyanate is crystallographically independent. Co-N(CS) is short (1.91(2) &#506;); Co-N(H3) being 1.96(2) &#506;. Only one crystallographically independent acetate species is found, lying close to a coplanar, centrosymmetrically related image to which it is presumably bound by a hydrogen bond (O...O 2.40(4) &#506;). 
ER  -

