
TY  - JOUR
A1  - Kooner, ZS 
A1  - Fenby, DV 
T1  - Vapour pressure study of the deuterium exchange reaction in methanol-ethanol systems: equilibrium constant determination
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1980
VL  - 33
IS  - 9
SP  - 1943
EP  - 1946
KW  - 
UR  - https://doi.org/10.1071/CH9801943 
N2  - The equilibrium constant of the reaction                        CH3OH(1)+C2H5OD(1) &#8594; CH3OD(1)+C2H5OH(1) is obtained from vapour pressure measurements on methanol+ethanol systems. The value obtained, 1.03±0.01 at 298 K, is in good agreement with that calculated independently from previously reported vapour pressure studies of water+methanol and water+ethanol systems. Vapour pressures at 298.15 K are reported for the systems CH3OH+C2H5OH, CH3OH+C2H5OD, CH3OD+C2H5OH and CH3OD+C2H5OD. Molar excess Gibbs functions are obtained from these vapour pressures. 
ER  -

