
TY  - JOUR
A1  - Crane, SG 
A1  - Easteal, AJ 
T1  - Acidity of hyperconcentrated electrolyte solutions. Hammett acidity function measurements for aqueous ZnCl<sub>2</sub>, + LiCl solutions
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1980
VL  - 33
IS  - 10
SP  - 2325
EP  - 2329
KW  - 
UR  - https://doi.org/10.1071/CH9802325 
N2  - The Hammett acidity function has been evaluated by means of spectrophotometric measurements with thymol blue indicator for (1-x)(ZnCl2,RH2O)+x(LiCl,RH2O) pseudobinary mixtures where R is 4 and 6. The pseudobinary mixtures have well defined minimum acidity near the composition (x = 0.67) which corresponds to the tetrachlorozincate ion stoichiometry. The acidity data for these mixtures support the conclusion that the properties of mixtures with R &#8804; 6 are dominated by formation of tetrachlorozincate anions. 
ER  -

