
%0 Journal Article
%A Guthrie, RD 
%A Jenkins, ID 
%A Watters, JJ 
%T 1'-Derivatives of sucrose and their acid hydrolysis
%J Australian Journal of Chemistry
%D 1980/11/01
%V 33
%N 11
%P 2487-2497
%K 
%R https://doi.org/10.1071/CH9802487
%U https://www.publish.csiro.au/paper/CH9802487 
%X Syntheses of 1'-chloro-1'-deoxy- and 1'-deoxy-sucrose are described. Several routes were investigated, the most successful being through 6,1',6'-tri-O-(2,4,6-trimethylbenzenesulfonyl)sucrose. Attempts to prepare 1'-deoxy-1'-fluorosucrose were unsuccessful. The rates of the acid-catalysed hydrolysis of 1'-chloro-1'-deoxysucrose and of 1'- deoxysucrose have been measured. These values are compared with that for sucrose itself. The mechanism of the hydrolyses is discussed. 
