
TY  - JOUR
A1  - Dance, IG 
A1  - Guerney, PJ 
T1  - Lead thiolates. The formation of water-soluble lead(II) thiolates and the crystal structure of 2-(Morpholin-4-yl)ethanethiolatolead(II) nitrate
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1981
VL  - 34
IS  - 1
SP  - 57
EP  - 64
KW  - 
UR  - https://doi.org/10.1071/CH9810057 
N2  - The solubilized thiolate ligand 2-(morpholin-4-yl)ethanethiolate, mes, and its ammonium conjugate acid, Hmes, form crystalline complexes Pb2(Hmes)3(N03)4, Pb(mes)2, Pb(mes)(N03), Pb(mes)- (O2CCH3) and Pb(mes)(O2CCF3). These lead(II) thiolate complexes are soluble in aqueous media. Crystals of Pb(mes)(NO3) contain chains of alternating lead and bridging thiolate sulfur atoms [Pb-S 2.646(4), 2.793(4) Å], with the lead coordinated also by the tertiary nitrogen atom [Pb-N 2.61(1) Å]. The nitrate ions weakly bridge lead atoms along the chain [Pb-O 2.69(2), 2.88(2), 2.98(2), 3.03(2) Å]. Crystal data: Pbca, a l3.396(2), b 21.900(3), c 7.348(1) Å, Z 8(x PbSN2O4- C6H12), 1602 observed data, R 0.057. 
ER  -

