
TY  - JOUR
A1  - Coller, BAW 
A1  - Jackson, WR 
A1  - Stragalinou, A 
A1  - Strauss, JUG 
T1  - The stereochemistry of organometallic compounds. XX. The stereochemistry of formation of (1-3-&#951;)-PdCl complexes from Deutero-substituted1-acetyl-4-t-butylcyclohex-1-enes
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1981
VL  - 34
IS  - 1
SP  - 171
EP  - 180
KW  - 
UR  - https://doi.org/10.1071/CH9810171 
N2  - The preparation and assignment of stereochemistry of some deutero-substituted 1-acetyl-4-t-butyl- cyclohex-1-enes is described. The formation of (1-3-&#951;)-PdCl complexes from these compounds is accompanied by a non-stereoselective loss of H and D, in agreement with a mechanism of formation which involves an initial palladium-assisted enolization of the ketone. 
ER  -

