
TY  - JOUR
A1  - Ferber, PH 
A1  - Gream, GE 
T1  - The 9-decalyl and related cations. VI. Solvolysis of Pent-4-enyl p-nitrobenzenesulfonate in 1,1,1,3,3,3-Hexafluoropropan-2-ol and of 3-(Cyclohex-1'-enyl)propyl p-Nitrobenzenesulfonate in 2,2,2-trifluoroethanol and 1,1,1,3,3,3-hexafluoropropan-2-ol
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1981
VL  - 34
IS  - 5
SP  - 1051
EP  - 1061
KW  - 
UR  - https://doi.org/10.1071/CH9811051 
N2  - Kinetic and product studies have established that pent-4-enyl p-nitrobenzenesulfonate undergoes insignificant solvolysis (1.5 %) by the &#960;-route in 1,1,1,3,3,3-hexafluoropropan-2-ol. &#960;-Participation to give the perhydroinden-3a-yl (8-hydrindyl) cation during the solvolysis of 3-(cyclohex-1'-enyl)propylp-nitrobenzenesulfonate, a substituted pent-4-enyl derivative, in fluorinated alcohols is, however, significant. In buffered 2,2,2-trifluoroethanol, it occurs to the extent of 30%; in buffered and unbuffered 1,1,1,3,3,3-hexafluoropropan-2-ol, the values are 96 and 98 %, respectively. 
ER  -

