
TY  - JOUR
A1  - Packer, JE 
A1  - Monig, J 
A1  - Dobson, BC 
T1  - Free-radical reductions of arenediazonium ions in aqueous solution. V. Pulse-radiolytic determination of rate constants for some <I>para</I>-substitutedbenzenediazonium ions
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1981
VL  - 34
IS  - 7
SP  - 1433
EP  - 1441
KW  - 
UR  - https://doi.org/10.1071/CH9811433 
N2  - Some rate constants for the reduction of para-substituted benzenediazonium ions by the radicals eaq-, &#183;CH2OH, (CH3)2&#183;COH and some semiquinone radical anions have been measured. The substituent group has no effect on the rates with eaq-, but as the reduction potential of the reducing radical becomes more positive, the substituent effect increases, electron-withdrawing groups enhancing the rates. No free halide is formed on reduction of p-BrC6H4N2+ or p-IC6H4N2+ by eaq- or &#183;CH2OH. 
ER  -

