
%0 Journal Article
%A Arthur, NL 
%A David, LF 
%T Reactions of trifluoromethyl radicals. VI. Hydrogen abstraction from trifluoroacetic acid and trifluoroacetic (<sup>2</sup>H<sub>1</sub>)acid
%J Australian Journal of Chemistry
%D 1981/07/01
%V 34
%N 7
%P 1535-1538
%K 
%R https://doi.org/10.1071/CH9811535
%U https://www.publish.csiro.au/paper/CH9811535 
%X The hydrogen abstraction reactions of CF3 radicals with CF3COOH and CF3COOD CF3 + CF3COOH &#8594; CF3H + CF3COO                 (1)CF3 + CF3COOD &#8594; CF3D + CF3COO                 (2) have been studied in the temperature ranges 102-225&#176;C and 153-275&#176;C respectively. The rate constants, based on the value of 1013.36 cm3 mol-1 s-1 for the recombination of CF3 radicals, are given by (k in cm3 mol-1 s-1 and E in J mol-1):  logk1 = (10.17±0.12)-(33140±970)/19.145T                      logk2 = (9.51±0.11)-(46090±1010)/19.145T 
