
TY  - JOUR
A1  - Finney, AJ 
A1  - Hitchman, MA 
A1  - Kepert, DL 
A1  - Raston, CL 
A1  - Rowbottom, GL 
A1  - White, AH 
T1  - Structural and spectroscopic studies of transition metal nitrite complexes. X. Crystal structures of <I>cis</I>-Bis(2,2'-bipyridine)(nitrito-O,O')nickel(II) nitrate and hydrated Tris(2,2'-bipyridine)nickel(II) nitrite/nitrate and sulfate. Stereochemistry of the [M(bidentate ligand)<sub>2</sub>(bidentate ligand')<sub>1</sub>] system
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1981
VL  - 34
IS  - 10
SP  - 2177
EP  - 2187
KW  - 
UR  - https://doi.org/10.1071/CH9812177 
N2  - The crystal structures of the title compounds are reported. In all cases, the coordination sphere of the nickel atom comprises three bidentate ligands. In (1), [Ni(bpy)2(O2N)] NO3, (Ni-N) is 2.M2 Å although there are small differences between those nitrogen atoms trans to the nitrite oxygen atoms and the other two. (Ni-O) is 2.12 Å. In (2), [Ni(bpy)3] NO2/NO3,xH2O, and (3), [Ni(bpy)3]- SO4,7.5H2O, a redetermination, Ni-N is shown to be c. 2.09 Å; serious disorder is present among the non-cationic components of (2), precluding a definite assignment of stoichiometry. 
ER  -

