
%0 Journal Article
%A Manas, AB 
%A Smith, RAJ 
%A Simpson, J 
%T Conformational analysis of the products of 1,4 addition of Tri(phenylthio)methyllithium to &#945;,&#946;-unsaturated ketones. The X-ray structuredetermination of 4-Phenyl-5,5,5-tri(phenylthio)pentan-2-one
%J Australian Journal of Chemistry
%D 1981/12/01
%V 34
%N 12
%P 2671-2676
%K 
%R https://doi.org/10.1071/CH9812671
%U https://www.publish.csiro.au/paper/CH9812671 
%X Iterative analysis of the second-order ABX spin system in the 1H n.m.r. of the title compound gave coupling constants which are consistent with a conformation involving a H-C-C-H dihedral angle of about 90º. The structure was confirmed by X-ray analysis. The 1H n.m.r. of the related compounds 2,2-dimethyl-5-pheny1-6,6,6-tri(phenylthio)hexan-3-one and 1,3-diphenyl-4,4,4-tri(pheny1-thio)butan-1-one were also analysed and found to have similar conformational characteristics. 
