
TY  - JOUR
A1  - Manas, AB 
A1  - Smith, RAJ 
A1  - Simpson, J 
T1  - Conformational analysis of the products of 1,4 addition of Tri(phenylthio)methyllithium to &#945;,&#946;-unsaturated ketones. The X-ray structuredetermination of 4-Phenyl-5,5,5-tri(phenylthio)pentan-2-one
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1981
VL  - 34
IS  - 12
SP  - 2671
EP  - 2676
KW  - 
UR  - https://doi.org/10.1071/CH9812671 
N2  - Iterative analysis of the second-order ABX spin system in the 1H n.m.r. of the title compound gave coupling constants which are consistent with a conformation involving a H-C-C-H dihedral angle of about 90º. The structure was confirmed by X-ray analysis. The 1H n.m.r. of the related compounds 2,2-dimethyl-5-pheny1-6,6,6-tri(phenylthio)hexan-3-one and 1,3-diphenyl-4,4,4-tri(pheny1-thio)butan-1-one were also analysed and found to have similar conformational characteristics. 
ER  -

