
%0 Journal Article
%A Canty, Allan J. 
%A Jin, Hong 
%A Skelton, Brian W. 
%A White, Allan H. 
%T Platinum&ndash;Tin Bonded Complexes, Including a Structural Analysis of the Octahedral Tris(pyrazol-1-yl)borate Complex Pt(SnMe<emph tye="8">3</emph>)Me<emph tye="8">2</emph>{(pz)<emph tye="8">3</emph>BH-<emph type="2">N</emph>,<emph type="2">N</emph>',<emph type="2">N</emph>"}
%J Australian Journal of Chemistry
%D 1999/07/23
%V 52
%N 5
%P 417-420
%K 
%R https://doi.org/10.1071/CH98166
%U https://www.publish.csiro.au/paper/CH98166 
%X The platinum(II) complex K&#91;PtMe2 &#123;(pz)3BH-N,N&#8242;&#125;&#93; reacts with SnCl2Me2 to form Pt(SnClMe2)Me2- &#123;(pz)3BH-N,N&#8242; ,N&Prime;&#125; (&#91;(pz)3BH&#93;&#8211;=tris(pyrazol-1-yl)borate). The closely related complex Pt(SnMe3)Me2- &#123; (pz)3BH-N,N&#8242; ,N&Prime; &#125; has distorted octahedral geometry for platinum with Pt&#8211;Sn 2&#183;5727(8) &#197; . The Pt&#8211;N distance trans to the SnMe3 group &#91;2&#183;237(7) &#197;&#93; is longer than those trans to the Me groups &#91;2&#183;127(7) and 2&#183;131(6) &#197;&#93;, indicating for the trimethylstannyl group a trans influence which is higher than that for the methyl group. 
