
TY  - JOUR
A1  - Hicks, JR 
A1  - Reinsborough, VC 
T1  - Rate enhancement of the nickel(II)-pada complex formation in sodium alkanesulfonate micellar solutions
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1982
VL  - 35
IS  - 1
SP  - 15
EP  - 19
KW  - 
UR  - https://doi.org/10.1071/CH9820015 
N2  - Sodium alkanesulfonates (C9, C8, C7, and C6) in micellar solution have been used to enhance the rate of reaction between Niaq2+ and the bidentate ligand pyridine-2-azo-p-dimethylaniline (pada) at 298.2 K. A Berezin-like model has been used to account for the observed kinetic constants in terms of the binding constants of each of the reagents to the micelles and the reaction volume and the concentration of the micellar surfactant. For a given chain length, the alkanesulfonates are about 25 % less effective than alkyl sulfates in promoting the rate of reaction and the model accounts for this successfully. 
ER  -

